Isama Kazuo, Kawakami Tsuyoshi, Nishimura Tetsuji
Division of Environmental Chemistry, National Institute of Health Sciences, Tokyo, Japan.
Yakugaku Zasshi. 2011;131(7):1135-40. doi: 10.1248/yakushi.131.1135.
Harmful elements are used as stabilizers and colorants in synthetic resin products. Accidental ingestion of harmful elements from such synthetic resins by infants is a dangerous health hazard. The Japanese Food Sanitation Law and the International Standard ISO 8124-3 "Safety of toys-Part 3: Migration of certain elements" control the levels of migrated harmful elements, such as lead or cadmium, from infants toys. However, the levels of migrated harmful elements from household products that are not infants toys are not controlled, since they are not covered by the law or standard. Therefore, we investigated the level of eight harmful elements (antimony, arsenic, barium, cadmium, chromium, lead, mercury and selenium) migrated from household products made of synthetic resin that infants may swallow by mistake. The extraction test of ISO 8124-3: 2010 was executed in 135 products (total 150 specimens), and the concentration of these elements was measured by inductively coupled plasma mass spectroscopy (ICP-MS). As a result, 1810 mg/kg and 1660 mg/kg of lead, exceeding the maximum acceptable level of the ISO standard, migrated from two products. In addition, lead and/or chromium at levels more than 1/10 of the maximum acceptable levels of the ISO standard migrated from four products. Household products that infants may swallow by mistake should ideally not release harmful elements such as lead and chromium.
有害元素被用作合成树脂产品的稳定剂和着色剂。婴儿意外摄入此类合成树脂中的有害元素会对健康造成危险。日本《食品卫生法》和国际标准ISO 8124-3《玩具安全 第3部分:特定元素的迁移》对婴儿玩具中迁移出的铅或镉等有害元素的含量进行管控。然而,非婴儿玩具类家用产品中迁移出的有害元素含量并未受到管控,因为它们不在该法律或标准的涵盖范围内。因此,我们对婴儿可能误吞的合成树脂制成的家用产品中迁移出的八种有害元素(锑、砷、钡、镉、铬、铅、汞和硒)的含量进行了调查。对135种产品(共150个样本)进行了ISO 8124-3:2010的萃取试验,并通过电感耦合等离子体质谱法(ICP-MS)测量了这些元素的浓度。结果,有两种产品迁移出的铅含量分别为1810毫克/千克和1660毫克/千克,超过了ISO标准的最大可接受水平。此外,有四种产品迁移出的铅和/或铬含量超过了ISO标准最大可接受水平的十分之一。婴儿可能误吞的家用产品理想情况下不应释放铅和铬等有害元素。