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316L不锈钢表面的正链烷酸单分子层可促进电聚合聚吡咯薄膜的附着。

n-Alkanoic acid monolayers on 316L stainless steel promote the adhesion of electropolymerized polypyrrole films.

作者信息

Shustak Galit, Domb Abraham J, Mandler Daniel

机构信息

Department of Inorganic and Analytical Chemistry, Hebrew University of Jerusalem, Jerusalem 91904, Israel.

出版信息

Langmuir. 2006 Jun 6;22(12):5237-40. doi: 10.1021/la060460r.

DOI:10.1021/la060460r
PMID:16732646
Abstract

The formation of a self-assembled monolayer significantly promotes the adhesion of electrodeposited polypyrrole on stainless steel. The monolayer affects the nucleation and growth mechanism of polypyrrole as a result of its hydrophobic nature. This was confirmed by analyzing current-time transients of the initial stages of electropolymerization and was in agreement with AFM images.

摘要

自组装单分子层的形成显著促进了电沉积聚吡咯在不锈钢上的附着。由于其疏水性，该单分子层影响了聚吡咯的成核和生长机制。通过分析电聚合初始阶段的电流-时间瞬变证实了这一点，并且与原子力显微镜图像一致。

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