来自干香柏（柏科）的新木脂素糖苷。

New lignan glycosides from Cupressus duclouxian (Cupessaceae).

作者信息

Xu Jian-Feng, Cao De-Hua, Tan Ning-Hua, Liu Zhi-Li, Zhang Yu-Mei, Yang Ya-Bin

机构信息

School of Life Science, Nanjing University, Nanjing 210093, Jiangsu, China.

出版信息

J Asian Nat Prod Res. 2006 Jan-Mar;8(1-2):181-5. doi: 10.1080/1028602042000325564.

DOI:10.1080/1028602042000325564

PMID:16753802

Abstract

From the branches and leaves of Cupressus duclouxiana two new lignan glycosides named cupressoside A (1) and cupressoside B (2), together with matairesinoside (3), dihydrodehydrodiconiferyl alcohol (4), dihydrodehydrodiconiferyl alcohol-9-O-alpha-L-rhamnopyranoside (5), dihydrodehydrodiconiferyl alcohol-4-O-alpha-L-rhamnopyranoside (6), ( - )-isolariciresinol (7) and ( - )-isolariciresinol-9-O-beta-D-xylopyranoside (8), were isolated. The structures of these compounds were determined on the basis of their HR-FAB-MS, IR, UV, 1H and 13C NMR (DEPT), and 2D NMR (HMQC, HMBC, COSY, NOESY) spectral data.

摘要

从高山柏的枝叶中分离得到了两种新的木脂素苷，分别命名为柏木苷A（1）和柏木苷B（2），以及异落叶松脂醇苷（3）、二氢脱氢二松柏醇（4）、二氢脱氢二松柏醇-9-O-α-L-鼠李糖苷（5）、二氢脱氢二松柏醇-4-O-α-L-鼠李糖苷（6）、（-）-异落叶松脂醇（7）和（-）-异落叶松脂醇-9-O-β-D-木糖苷（8）。这些化合物的结构是根据它们的高分辨快原子轰击质谱（HR-FAB-MS）、红外光谱（IR）、紫外光谱（UV）、一维氢核磁共振谱（1H NMR）、一维碳核磁共振谱（13C NMR）（DEPT）以及二维核磁共振谱（2D NMR）（HMQC、HMBC、COSY、NOESY）光谱数据确定的。