使用9-苯基-10-甲基吖啶通过分子氧将苯甲醇无溶剂选择性光催化氧化为苯甲醛
Solvent-free selective photocatalytic oxidation of benzyl alcohol to benzaldehyde by molecular oxygen using 9-phenyl-10-methylacridinium.
作者信息
Ohkubo Kei, Suga Kyou, Fukuzumi Shunichi
机构信息
Department of Material and Life Science, Graduate School of Engineering, Osaka University, SORST, Japan Science and Technology Agency (JST), Suita, Osaka, 565-0871, Japan.
出版信息
Chem Commun (Camb). 2006 May 21(19):2018-20. doi: 10.1039/b518127e. Epub 2006 Apr 11.
DOI:10.1039/b518127e
PMID:16767261
Abstract
9-Phenyl-10-methylacridium ion acts as an effective photocatalyst for solvent free selective photocatalytic oxidation of benzyl alcohol to benzaldehyde under visible light irradiation via efficient photoinduced electron transfer from benzyl alcohol to the singlet excited state of the acridinium ion.
摘要
9-苯基-10-甲基吖啶离子在可见光照射下，通过苄醇向吖啶离子单重激发态的有效光致电子转移，作为一种有效的光催化剂，用于在无溶剂条件下将苄醇选择性光催化氧化为苯甲醛。
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