Rashed M N
Chemistry Department, Faculty of Science, 81528, Aswan, Egypt.
Environ Monit Assess. 2006 Aug;119(1-3):31-41. doi: 10.1007/s10661-005-9002-y. Epub 2006 Jun 13.
Lead, one of the earliest metals recognized and used by humans, has a long history of beneficial use. However, it is now recognized as toxic and as posing a widespread threat to humans and wildlife. Treatment of lead from polluted water and wastewater has received a great deal of attention. Adsorption is one of the most common technologies for the treatment of lead-polluted water. This technique was evaluated here, with the goal of identifying innovative, low-cost adsorbent. This study presents experiments undertaken to determine the suitable conditions for the use of peach and apricot stones, produced from food industries as solid waste, as adsorbents for the removal of lead from aqueous solution. Chemical stability of adsorbents, effect of pH, adsorbents dose, adsorption time and equilibrium concentration were studied. The results reveal that adsorption of lead ions onto peach stone was stronger than onto apricot stone up to 3.36% at 3 h adsorption time. Suitable equilibrium time for the adsorption was 3-5 h (% Pb adsorption 93% for apricot and 97.64% for peach). The effective adsorption range for pH in the range was 7-8. Application of Langmuir and Freundlich isotherm models show high adsorption maximum and binding energies for using these adsorbents for the removal of lead ions from contaminated water and wastewater.
铅是人类最早认识和使用的金属之一,有着长期的有益使用历史。然而,现在它被认为是有毒的,并且对人类和野生动物构成广泛威胁。从受污染的水和废水中去除铅受到了极大关注。吸附是处理铅污染水最常用的技术之一。在此对该技术进行评估,目的是确定创新的低成本吸附剂。本研究开展了实验,以确定将食品工业产生的桃核和杏核作为固体废物用作从水溶液中去除铅的吸附剂的合适条件。研究了吸附剂的化学稳定性、pH值、吸附剂剂量、吸附时间和平衡浓度的影响。结果表明,在吸附3小时时,铅离子在桃核上的吸附比在杏核上更强,高达3.36%。吸附的合适平衡时间为3至5小时(杏核的铅吸附率为93%,桃核为97.64%)。该范围内pH的有效吸附范围为7至8。朗缪尔等温线模型和弗伦德里希等温线模型的应用表明,使用这些吸附剂从受污染的水和废水中去除铅离子具有较高的吸附最大值和结合能。