Hoogenboom Richard, Schubert Ulrich S
Laboratory of Macromolecular Chemistry and Nanoscience, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The Netherlands.
Chem Soc Rev. 2006 Jul;35(7):622-9. doi: 10.1039/b515911c. Epub 2006 Mar 9.
The introduction of supramolecular interactions in synthetic polymers seems to be a promising approach towards novel 'smart' materials that combine both the (reversible) supramolecular interactions and the properties of the polymers. In this tutorial review, the use of (metallo-)supramolecular initiators for the preparation of end-functionalized (metallo-)supramolecular polymers will be discussed in detail. The different polymerization techniques that have been applied as well as the different ligands and metal complexes that were used to initiate these polymerizations will be discussed together with the resulting polymer properties.
在合成聚合物中引入超分子相互作用似乎是一种制备新型“智能”材料的有前途的方法，这种材料兼具（可逆的）超分子相互作用和聚合物的特性。在本教程综述中，将详细讨论使用（金属）超分子引发剂制备末端官能化（金属）超分子聚合物的方法。将讨论已应用的不同聚合技术以及用于引发这些聚合反应的不同配体和金属配合物，以及所得聚合物的性能。
