Britz David A, Khlobystov Andrei N
Department of Materials, University of Oxford, Parks Road, Oxford, UK OX1 3PH.
Chem Soc Rev. 2006 Jul;35(7):637-59. doi: 10.1039/b507451g. Epub 2006 Mar 23.
In this critical review we survey non-covalent interactions of carbon nanotubes with molecular species from a chemical perspective, particularly emphasising the relationship between the structure and dynamics of these structures and their functional properties. We demonstrate the synergistic character of the nanotube-molecule interactions, as molecules that affect nanotube properties are also altered by the presence of the nanotube. The diversity of mechanisms of molecule-nanotube interactions and the range of experimental techniques employed for their characterisation are illustrated by examples from recent reports. Some practical applications for carbon nanotubes involved in non-covalent interactions with molecules are discussed.
在这篇批判性综述中，我们从化学角度审视了碳纳米管与分子物种的非共价相互作用，特别强调了这些结构的结构与动力学及其功能特性之间的关系。我们展示了纳米管 - 分子相互作用的协同特性，因为影响纳米管性质的分子也会因纳米管的存在而发生改变。通过近期报告中的实例，说明了分子 - 纳米管相互作用机制的多样性以及用于表征它们的一系列实验技术。讨论了涉及与分子非共价相互作用的碳纳米管的一些实际应用。
