Fivefold symmetry in superlattices of monolayer-protected gold nanoparticles.

Three-dimensional (3D) superlattices of gold nanoparticles were prepared at an air/solution interface. The surface of the gold nanoparticles used is protected by N-acetylglutathione (NAG). Morphological studies revealed that the superlattices formed fivefold symmetric structures such as pentagonal rod, decahedron, and icosahedron, which were probably developed by multiple twinning. Moreover, high-resolution surface images of the superlattices in fivefold symmetry showed excellent ordered arrangements of nanoparticles with both close-packed and non-close-packed structures.