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A general and efficient palladium-catalyzed intramolecular cyclization reaction of beta-brominated porphyrins.

作者信息

Shen Dong-Mei, Liu Chao, Chen Qing-Yun

机构信息

Key laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China.

出版信息

J Org Chem. 2006 Aug 18;71(17):6508-11. doi: 10.1021/jo0609677.

DOI:10.1021/jo0609677
PMID:16901136
Abstract

A general and efficient synthesis of fused five-membered porphyrins from the readily available beta-brominated porphyrins via palladium-catalyzed intramolecular cyclization has been developed, which can be applied for various metal complexes of beta-brominated porphyrins or free base ones and generally results in good yields of the fused five-membered porphyrins.

摘要

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