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catena-Poly[[[triaquasulfatocobalt(II)]-mu-4,4'-bipyridine] ethane-1,2-diol solvate].

作者信息

Lu Wen-Jie, Zhu Yi-Min, Zhong Kai-Long

机构信息

Department of Chemical and Environmental Engineering, Wuyi University, Jiangmen, Guangdong Province, People's Republic of China.

出版信息

Acta Crystallogr C. 2006 Sep;62(Pt 9):m448-50. doi: 10.1107/S0108270106031520. Epub 2006 Aug 31.

DOI:10.1107/S0108270106031520
PMID:16954633
Abstract

In the title compound, {[Co(SO4)(C10H8N2)(H2O)3].C2H6O2}n, each CoII center is octahedrally coordinated by two N atoms from two bridging 4,4'-bipyridine (bipy) ligands and four O atoms, one from a monodentate sulfate ligand and three from aqua ligands. The bipy ligands occupy special positions of site symmetry -1 and bridge adjacent cobalt(II) centers to form one-dimensional linear coordination chains. Adjacent chains are arranged in a cross-like fashion around the mid-point of the bipy ligands, resulting in a three-dimensional supramolecular array.

摘要

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