双（2,2'-联吡啶-κN,N'）（硫酸根-κO,O'）钴（II）乙二醇单溶剂合物
Bis(2,2'-bipyridyl-κN,N')(sulfato-κO,O')cobalt(II) ethane-1,2-diol monosolvate.
作者信息
Zhong Kai-Long, Pan Xian-Xiao, Cao Guo-Qing, Chen Lin
机构信息
Department of Applied Chemistry, Nanjing College of Chemical Technology, Nanjing 210048, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 8;67(Pt 1):m43. doi: 10.1107/S1600536810050592.
The title compound, [Co(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), has the Co(2+) ion in a distorted octa-hedral CoN(4)O(2) coordination geometry. A twofold rotation axis passes through the Co and S atoms, and through the mid-point of the C-C bond of the ethane-diol mol-ecule. In the crystal, the [CoSO(4)(C(10)H(8)N(2))(2)] and C(2)H(6)O(2) units are held together by a pair of O-H⋯O hydrogen bonds.
标题化合物[Co(SO₄)(C₁₀H₈N₂)₂]·C₂H₆O₂中，Co²⁺离子具有扭曲的八面体CoN₄O₂配位几何结构。一个二重旋转轴穿过Co和S原子，以及乙二二醇分子C—C键的中点。在晶体中，[CoSO₄(C₁₀H₈N₂)₂]和C₂H₆O₂单元通过一对O—H⋯O氢键连接在一起。
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