Descalzo Ana B, Martínez-Máñez Ramón, Sancenón Félix, Hoffmann Katrin, Rurack Knut
Departamento de Química, Instituto de Química Molecular Aplicada, Universidad Politécnica de Valencia, Camino de Vera s/n, 46071 Valencia, Spain.
Angew Chem Int Ed Engl. 2006 Sep 11;45(36):5924-48. doi: 10.1002/anie.200600734.
The combination of nanomaterials as solid supports and supramolecular concepts has led to the development of hybrid materials with improved functionalities. These "hetero-supramolecular" ideas provide a means of bridging the gap between molecular chemistry, materials sciences, and nanotechnology. In recent years, relevant examples have been reported on functional aspects, such as enhanced recognition and sensing by using molecules on preorganized surfaces, the reversible building of nanometer-sized networks and 3D architectures, as well as biomimetic and gated chemistry in hybrid nanomaterials for the development of advanced functional protocols in three-dimensional frameworks. This approach allows the fine-tuning of the properties of nanomaterials and offers new perspectives for the application of supramolecular concepts.
将纳米材料用作固体载体与超分子概念相结合，已促使具有改进功能的杂化材料得到发展。这些“杂化超分子”理念提供了一种弥合分子化学、材料科学和纳米技术之间差距的方法。近年来，已报道了有关功能方面的相关实例，例如通过在预组织表面使用分子来增强识别和传感、纳米尺寸网络和三维结构的可逆构建，以及用于在三维框架中开发先进功能方案的杂化纳米材料中的仿生化学和门控化学。这种方法能够对纳米材料的性质进行微调，并为超分子概念的应用提供了新的视角。
