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基于反应活性的溶剂型产品挥发性有机化合物控制:更有效的臭氧减排策略

Reactivity-based VOC control for solvent products: more efficient ozone reduction strategies.

作者信息

Avery Robert J

机构信息

PCA Services Inc, Durham, North Carolina 27705, USA.

出版信息

Environ Sci Technol. 2006 Aug 15;40(16):4845-50. doi: 10.1021/es060296u.

Abstract

It has been almost 40 years since scientists and regulators began to publicly recognize that volatile organic compounds (VOCs) differ in their potential to form ozone. Since 1977, our understanding of the mechanisms by which VOCs contribute to ozone formation has grown substantially. An assessment of the science indicates that we now have sufficient understanding to develop and implement a more efficient approach to VOC control policy that will promote smarter, more cost-effective VOC controls. Furthermore, the U.S. Environmental Protection Agency's recently published Interim Guidance on Control of Volatile Organic Compounds in Ozone State Implementation Plans "encourages States to consider recent scientific information on the photochemical reactivity of volatile organic compounds (VOC) in the development of State implementation plans (SIPs)." As has been demonstrated by the California Air Resources Board's Aerosol Coatings Rule and the recent experience in Houston addressing high-reactivity VOCs, reactivity-based regulations may be more effective and efficient than mass-based rules in many applications. It is time for regulators, industry, and other stakeholders to work togetherto accelerate efforts to bring about a new paradigm in VOC control, in which the focus is on the ozone-forming potential of VOC emissions, rather than the mass of VOCs emitted.

摘要

自科学家和监管机构开始公开承认挥发性有机化合物(VOCs)在形成臭氧的潜力方面存在差异以来,已经过去了近40年。自1977年以来,我们对VOCs促成臭氧形成的机制的理解有了显著增长。对相关科学的评估表明,我们现在已经有了足够的理解,可以制定并实施一种更有效的VOC控制政策方法,以促进更明智、更具成本效益的VOC控制。此外,美国环境保护局最近发布的《臭氧国家实施计划中挥发性有机化合物控制临时指南》“鼓励各州在制定州实施计划(SIPs)时考虑有关挥发性有机化合物(VOC)光化学反应性的最新科学信息”。正如加利福尼亚空气资源委员会的气雾剂涂料规则以及休斯顿近期处理高反应性VOCs的经验所表明的那样,在许多应用中,基于反应性的法规可能比基于质量的规则更有效。现在是监管机构、行业和其他利益相关者共同努力的时候了,以加速实现VOC控制新范式的努力,在这种范式中,重点是VOC排放形成臭氧的潜力,而不是所排放VOCs的质量。

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