Wang Xun, Li Yadong
Department of Chemistry, Tsinghua University, Beijing 100084, People's Republic of China.
Inorg Chem. 2006 Sep 18;45(19):7522-34. doi: 10.1021/ic051885o.
One-dimensional (1-D) nanostructures of materials have received great research attention because of their unique photochemistry, photophysical, and electron-transport properties different from those of bulky or nanoparticle materials. One of the main challenges in this field is how to precisely control the sizes, dimensionalities, compositions, and crystal structures of materials in nanoscale. This review summarizes the recent progress in the solution-based routes to prepare 1-D nanostructures, highlighting the contribution from this laboratory. Crystal structure as one of the inherent factors that may determine the growth behavior of the nanocrystals is emphasized in this paper. Particularly compounds with layered structures or anistropic crystal structures are given special attention in the controlled growth of 1-D nanostructures. This review aims to present a relatively general understanding of the correlation between the crystal structure and growth behavior of materials under solution-based conditions and show how to choose appropriate conditions for the growth of 1-D nanostructures.
一维(1-D)材料纳米结构因其具有不同于块状或纳米颗粒材料的独特光化学、光物理和电子传输特性而受到了广泛的研究关注。该领域的主要挑战之一是如何在纳米尺度上精确控制材料的尺寸、维度、组成和晶体结构。本综述总结了基于溶液法制备一维纳米结构的最新进展,突出了本实验室所做的贡献。本文强调了晶体结构作为可能决定纳米晶体生长行为的内在因素之一。特别是具有层状结构或各向异性晶体结构的化合物在一维纳米结构的可控生长中受到了特别关注。本综述旨在对基于溶液条件下材料的晶体结构与生长行为之间的相关性给出一个相对全面的认识,并展示如何选择合适的条件来生长一维纳米结构。