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电催化和光催化中的纳米限域效应

Nanoconfinement Effects in Electrocatalysis and Photocatalysis.

作者信息

Bie Chuanbiao, Yang Jindi, Zeng Xiangkang, Wang Zhuyuan, Sun Xin, Yang Zhe, Yu Jiaguo, Zhang Xiwang

机构信息

Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, 68 Jincheng Street, Wuhan, 430078, P. R. China.

UQ Dow Centre for Sustainable Engineering Innovation, School of Chemical Engineering, The University of Queensland, St Lucia, QLD, 4072, Australia.

出版信息

Small. 2025 Apr;21(13):e2411184. doi: 10.1002/smll.202411184. Epub 2025 Feb 24.

DOI:10.1002/smll.202411184
PMID:39989153
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11962712/
Abstract

Recently, the enzyme-inspired nanoconfinement effect has garnered significant attention for enhancing the efficiency of electrocatalysts and photocatalysts. Despite substantial progress in these fields, there remains a notable absence of comprehensive and insightful articles providing a clear understanding of nanoconfined catalysts. This review addresses this gap by delving into nanoconfined catalysts for electrocatalytic and photocatalytic energy conversion. Initially, the effect of nanoconfinement on the thermodynamics and kinetics of reactions is explored. Subsequently, the primary and secondary structures of nanoconfined catalysts are categorized, their properties are outlined, and typical methods for their construction are summarized. Furthermore, an overview of the state-of-the-art applications of nanoconfined catalysts is provided, focusing on reactions of hydrogen and oxygen evolution, oxygen reduction, carbon dioxide reduction, hydrogen peroxide production, and nitrogen reduction. Finally, the current challenges and future prospects in nanoconfined catalysts are discussed. This review aims to provide in-depth insights and guidelines to advance the development of electrocatalytic and photocatalytic energy conversion technology by nanoconfined catalysts.

摘要

最近，受酶启发的纳米限域效应在提高电催化剂和光催化剂效率方面引起了广泛关注。尽管这些领域取得了重大进展，但仍然明显缺乏全面且有深度的文章来清晰地阐述纳米限域催化剂。本综述通过深入研究用于电催化和光催化能量转换的纳米限域催化剂来填补这一空白。首先，探讨了纳米限域对反应热力学和动力学的影响。随后，对纳米限域催化剂的一级和二级结构进行了分类，概述了它们的性质，并总结了其构建的典型方法。此外，还提供了纳米限域催化剂的最新应用概述，重点关注析氢、析氧、氧还原、二氧化碳还原、过氧化氢生成和氮还原反应。最后，讨论了纳米限域催化剂当前面临的挑战和未来前景。本综述旨在提供深入的见解和指导方针，以推动纳米限域催化剂在电催化和光催化能量转换技术方面的发展。

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