利用微混合技术通过电化学产生的I⁺对芳香族化合物进行选择性单碘化反应。
Selective monoiodination of aromatic compounds with electrochemically generated I+ using micromixing.
作者信息
Midorikawa Koji, Suga Seiji, Yoshida Jun-ichi
机构信息
Technology Laboratory, Nippoh Chemicals Co., Ltd., Chiba, 298-0104, Japan.
出版信息
Chem Commun (Camb). 2006 Sep 28(36):3794-6. doi: 10.1039/b607284d. Epub 2006 Aug 3.
DOI:10.1039/b607284d
PMID:16969460
Abstract
Selective monoiodination of aromatic compounds such as dimethoxybenzene has been successfully achieved with I+, which is generated by anodic oxidation of I2 in acetonitrile, using micromixing.
摘要
使用微混合技术，通过碘在乙腈中的阳极氧化生成的I⁺已成功实现了对诸如二甲氧基苯等芳香族化合物的选择性单碘化。
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