Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan.
Molecules. 2019 Apr 18;24(8):1532. doi: 10.3390/molecules24081532.
Flow microreactors are expected to make a revolutionary change in chemical synthesis involving various fields of polymer synthesis. In fact, extensive flow microreactor studies have opened up new possibilities in polymer chemistry including cationic polymerization, anionic polymerization, radical polymerization, coordination polymerization, polycondensation and ring-opening polymerization. This review provides an overview of flow microreactors in anionic polymerization and their various applications.
流微反应器有望在涉及聚合合成各个领域的化学合成中带来革命性的变化。事实上,广泛的流微反应器研究在包括阳离子聚合、阴离子聚合、自由基聚合、配位聚合、缩聚和开环聚合在内的聚合化学领域开辟了新的可能性。本文综述了阴离子聚合中的流微反应器及其各种应用。