去溶剂化打破平衡：溶剂对芳香相互作用的影响
Desolvation tips the balance: solvent effects on aromatic interactions.
作者信息
Cockroft Scott L, Hunter Christopher A
机构信息
Centre for Chemical Biology, Krebs Institute for Biomolecular Science, Department of Chemistry, University of Sheffield, Sheffield, UKS3 7HF.
出版信息
Chem Commun (Camb). 2006 Sep 28(36):3806-8. doi: 10.1039/b608165g. Epub 2006 Aug 22.
DOI:10.1039/b608165g
PMID:16969464
Abstract
The folding behaviour of the molecular torsion balance framework is rationalised by considering the effects of solvation using the alpha/beta H-bond parameter scheme for estimating the free energies of pairwise functional group interactions in solution.
摘要
通过使用α/β氢键参数方案考虑溶剂化效应来合理化分子扭转平衡框架的折叠行为，该方案用于估计溶液中成对官能团相互作用的自由能。
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