通过1,3 - 二烯的氢铟化反应以及与羰基化合物的一锅法反应生成烯丙基铟。
Generation of allylic indium by hydroindation of 1,3-dienes and one-pot reaction with carbonyl compounds.
作者信息
Hayashi Naoki, Honda Hiroyuki, Yasuda Makoto, Shibata Ikuya, Baba Akio
机构信息
Research Center for Environmental Preservation, Osaka University, 2-4 Yamadaoka, Suita, Osaka 565-0871, Japan.
出版信息
Org Lett. 2006 Sep 28;8(20):4553-6. doi: 10.1021/ol061797n.
PMID:16986948
Abstract
A hydroindation of 1,3-dienes by dichloroindium hydride (HInCl2) generates allylic indiums that react with carbonyl or imine moieties in a one-pot treatment. The former reaction proceeds in a radical manner, and the latter is ionic allylation. Moreover, both reactions require no additives such as radical initiators, Lewis acids, or transition metal catalysts.
摘要
二氯氢化铟（HInCl2）对1,3 - 二烯进行氢化铟化反应生成烯丙基铟，后者在一锅法处理中能与羰基或亚胺部分发生反应。前一个反应以自由基方式进行，后一个反应是离子型烯丙基化反应。此外，这两个反应均无需自由基引发剂、路易斯酸或过渡金属催化剂等添加剂。
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