Department of Chemistry , University of Texas at Austin , Welch Hall A5300, 105 East 24th Street , Austin , Texas 78712 , United States.
Chem Rev. 2018 Jun 27;118(12):6026-6052. doi: 10.1021/acs.chemrev.8b00213. Epub 2018 Jun 13.
Metal-catalyzed reductive coupling has emerged as an alternative to the use of stoichiometric organometallic reagents in an increasingly diverse range of carbonyl and imine additions. In this review, the use of diene, allene, and enyne pronucleophiles in intermolecular carbonyl and imine reductive couplings are surveyed, along with related hydrogen autotransfer processes.
金属催化的还原偶联已成为替代使用化学计量有机金属试剂的一种方法,在越来越多的羰基和亚胺加成反应中得到了应用。在这篇综述中,调查了二烯、丙二烯和炔烃前体亲核试剂在分子间羰基和亚胺还原偶联中的应用,以及相关的氢自动转移过程。