Price B Katherine, Tour James M
Departments of Chemistry, and Mechanical Engineering and Materials Science, The Smalley Institute for Nanoscale Science and Technology, Rice University, MS-222, 6100 Main Street, Houston, TX 77005, USA.
J Am Chem Soc. 2006 Oct 4;128(39):12899-904. doi: 10.1021/ja063609u.
Single-walled carbon nanotubes (SWNTs) are exfoliated and functionalized into small bundles and individuals by vigorous stirring "on water" in the presence of a substituted aniline and an oxidizing agent. This is an example of an "on water" reaction that leads to functionalized SWNTs, and it represents a "green", or environmentally friendly, process. A variety of reaction conditions were explored. The products were analyzed with Raman, UV-vis-NIR, and X-ray photoelectron spectroscopies, atomic force and transmission electron microscopies, and thermogravimetric analysis.
单壁碳纳米管（SWNTs）在取代苯胺和氧化剂存在的情况下，通过在水中剧烈搅拌而被剥离并官能化形成小束和单个纳米管。这是一个“水相”反应的例子，该反应能生成官能化的单壁碳纳米管，它代表了一种“绿色”或环境友好型的工艺。研究了各种反应条件。通过拉曼光谱、紫外-可见-近红外光谱、X射线光电子能谱、原子力显微镜和透射电子显微镜以及热重分析对产物进行了分析。
