Delville A
Institut de Chimie Organique et de Biochimie, Université de Liège, Sart - Tilman par 4000 Liège, Belgium.
Biophys Chem. 1984 Mar;19(2):183-9. doi: 10.1016/0301-4622(84)85018-8.
We compare the numerous available data on ionic activities, in the presence of polyelectrolytes, with evaluation of these quantities from a modified Poisson-Boltzmann equation in the framework of a cell model. This treatment gives an excellent description of the mean activity for various ions. The activity of counterions is well-predicted, that of co-ions is generally overestimated.
我们将存在聚电解质时大量可用的离子活度数据，与在细胞模型框架下从修正的泊松 - 玻尔兹曼方程对这些量的评估进行了比较。这种处理方法对各种离子的平均活度给出了很好的描述。反离子的活度得到了很好的预测，而共离子的活度通常被高估。
