Ge Hai Yan, Zhang Yu Mei, Li Bao Long, Zhang Yong
Key Laboratory of Organic Synthesis Chemistry of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215123, People's Republic of China.
Acta Crystallogr C. 2006 Oct;62(Pt 10):m501-3. doi: 10.1107/S010827010603294X. Epub 2006 Sep 28.
The coordination geometry of the CdII atom in the title complex, [Cd(NCS)2(C12H12N6)2]n or [Cd(NCS)2(mbtz)2]n, where mbtz is 1,3-bis(1,2,4-triazol-1-ylmethyl)benzene, is a distorted compressed octahedron in which the CdII atom lies on an inversion centre, coordinated by four N atoms from the triazole rings of four mbtz ligands and two N atoms from two monodentate NCS- ligands. The structure is polymeric, with 24-membered spiro-fused rings extending along [100] and with the 24-membered ring containing two inversion-related mbtz molecules.
