Li Baolong, Li Baozong, Zhu Xia, Zhu Liming, Zhang Yong
College of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, People's Republic of China.
Acta Crystallogr C. 2003 Sep;59(Pt 9):m350-1. doi: 10.1107/s0108270103012435. Epub 2003 Aug 9.
The coordination geometry of the Zn(II) atom in the title complex, Zn(C(2)N(3))(2)(C(6)H(8)N(6))(2) or Zn(dca)(2)(bte)(2), where bte is mu-1,2-bis(1,2,4-triazol-1-yl)ethane and dca is dicyanamide, is distorted compressed octahedral, in which the Zn(II) atom lies on an inversion center and coordinates four N atoms from the triazole rings of four symmetry-related bte ligands and two N atoms from two symmetry-related monodentate dca ligands. The structure is polymeric, with 18-membered spiro-fused rings extending in the b direction and each 18-membered ring involving two inversion-related bte molecules.
在标题配合物[Zn(C₂N₃)₂(C₆H₈N₆)₂]ₙ或[Zn(dca)₂(bte)₂]ₙ中,锌(II)原子的配位几何形状为扭曲的压缩八面体,其中锌(II)原子位于一个反演中心,与四个对称相关的bte配体的三唑环中的四个氮原子以及两个对称相关的单齿dca配体中的两个氮原子配位。该结构为聚合物,18元螺稠环沿b方向延伸,每个18元环包含两个反演相关的bte分子。 其中bte为μ-1,2-双(1,2,4-三唑-1-基)乙烷,dca为双氰胺。