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无限双链链状聚合物链-聚[[双(二氰胺基)锌(II)]-二-μ-1,2-双(1,2,4-三唑-1-基)乙烷-κ4N4:N4']

The infinite double-stranded chain polymer catena-poly[[bis(dicyanamido)zinc(II)]-di-mu-1,2-bis(1,2,4-triazol-1-yl)ethane-kappa4N4:N4'].

作者信息

Li Baolong, Li Baozong, Zhu Xia, Zhu Liming, Zhang Yong

机构信息

College of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, People's Republic of China.

出版信息

Acta Crystallogr C. 2003 Sep;59(Pt 9):m350-1. doi: 10.1107/s0108270103012435. Epub 2003 Aug 9.

Abstract

The coordination geometry of the Zn(II) atom in the title complex, Zn(C(2)N(3))(2)(C(6)H(8)N(6))(2) or Zn(dca)(2)(bte)(2), where bte is mu-1,2-bis(1,2,4-triazol-1-yl)ethane and dca is dicyanamide, is distorted compressed octahedral, in which the Zn(II) atom lies on an inversion center and coordinates four N atoms from the triazole rings of four symmetry-related bte ligands and two N atoms from two symmetry-related monodentate dca ligands. The structure is polymeric, with 18-membered spiro-fused rings extending in the b direction and each 18-membered ring involving two inversion-related bte molecules.

摘要

在标题配合物[Zn(C₂N₃)₂(C₆H₈N₆)₂]ₙ或[Zn(dca)₂(bte)₂]ₙ中,锌(II)原子的配位几何形状为扭曲的压缩八面体,其中锌(II)原子位于一个反演中心,与四个对称相关的bte配体的三唑环中的四个氮原子以及两个对称相关的单齿dca配体中的两个氮原子配位。该结构为聚合物,18元螺稠环沿b方向延伸,每个18元环包含两个反演相关的bte分子。 其中bte为μ-1,2-双(1,2,4-三唑-1-基)乙烷,dca为双氰胺。

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