Lin Ai-Mei, Zhan Hong-Bing, Chen Wen-Zhe
College of Materials Science and Engineering, Fuzhou University, Fuzhou 350002, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2006 Jul;26(7):1306-9.
Nickel tetrasulfo-phthalocyanine (NiTSPc) was successfully doped into vinyltriethoxysilane (VTES)modified silicate gel glass by sol-gel technique, IR and UV-Vis spectral examination was carried out. The results show that vinyl has been introduced into SiO2 network, and the structure of gel glass is therefore changed. The encapsulation of NiTSPc does not make any noteworthy changes in the composition and structure of gel glass matrix. NiTSPc molecules are well dispersed in the organic modified matrix, and the phenomenon of aggregation is greatly suppressed.
通过溶胶-凝胶技术成功地将四磺酸基酞菁镍（NiTSPc）掺杂到乙烯基三乙氧基硅烷（VTES）改性的硅酸盐凝胶玻璃中，并进行了红外和紫外-可见光谱检测。结果表明，乙烯基已被引入到SiO₂网络中，从而改变了凝胶玻璃的结构。NiTSPc的包封并没有使凝胶玻璃基质的组成和结构发生任何显著变化。NiTSPc分子在有机改性基质中分散良好，聚集现象得到了极大抑制。
