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[四磺酸取代基对酞菁掺杂溶胶-凝胶杂化物紫外/可见吸收光谱的影响]

[Influence of tetrasulfo-substituents on the UV/Vis absorption spectra of phthalocyanine doped sol-gel hybrid].

作者信息

Zhan Hong-bing, Du Yu-hong, Lin Chun-ying, Zhao Xu-cheng, Qin Jing

机构信息

College of Materials Science and Engineering, Fuzhou University, Fuzhou 350002, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2005 Nov;25(11):1850-2.

PMID:16499062
Abstract

Nickle phthalocyanine(NiPc) and Nickle tetrasulfo-phthalocyanine (NiTSPc) were introduced respectively into silica gel matrix by sol-gel technique. Composites were produced and their UV/Vis spectra were measured. The results show that the introduction of soluble tetrasulfo-substituents can greatly increase the solubility of phthalocyanine molecule, which is helpful for the steady co-existence of phthalocyanine in sol-gel hybrid and therefore beneficial to the production of homogeneous composite.

摘要

通过溶胶-凝胶技术分别将镍酞菁(NiPc)和四磺酸基镍酞菁(NiTSPc)引入硅胶基质中。制备了复合材料并测量了其紫外/可见光谱。结果表明,可溶性四磺酸基取代基的引入可大大提高酞菁分子的溶解度,这有助于酞菁在溶胶-凝胶杂化体系中稳定共存,因此有利于制备均匀的复合材料。

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