Leuenberger Michael N, Mucciolo Eduardo R
NanoScience Technology Center, University of Central Florida, Orlando, FL 32826, USA.
Phys Rev Lett. 2006 Sep 22;97(12):126601. doi: 10.1103/PhysRevLett.97.126601. Epub 2006 Sep 18.
We show that it is possible to topologically induce or quench the Kondo resonance in the conductance of a single-molecule magnet (S>1/2) strongly coupled to metallic leads. This can be achieved by applying a magnetic field perpendicular to the molecule easy axis and works for both full- and half-integer spin cases. The effect is caused by the Berry-phase interference between two quantum tunneling paths of the molecule's spin. We have calculated the renormalized Berry-phase oscillations of the Kondo peaks as a function of the transverse magnetic field as well as the conductance of the molecule by means of the poor man's scaling method. We propose to use a new variety of the single-molecule magnet Ni4 for the experimental observation of this phenomenon.
我们表明,对于与金属引线强耦合的单分子磁体(S>1/2),在其电导中通过拓扑方式诱导或淬灭近藤共振是可能的。这可以通过施加垂直于分子易轴的磁场来实现,并且对于全整数和半整数自旋情况均有效。这种效应是由分子自旋的两条量子隧穿路径之间的贝里相位干涉引起的。我们通过穷人标度法计算了近藤峰的重整化贝里相位振荡作为横向磁场以及分子电导的函数。我们建议使用新型单分子磁体Ni4对这一现象进行实验观测。