电化学在π-碱性去芳构化试剂发展中的作用。

The role of electrochemistry in the development of pi-basic dearomatization agents.

作者信息

Surendranath Yogesh, Harman W Dean

机构信息

University of Virginia, Charlottesville, VA 22904-4319, USA.

出版信息

Dalton Trans. 2006 Sep 7(33):3957-65. doi: 10.1039/b607694g. Epub 2006 Jul 26.

DOI:10.1039/b607694g

PMID:17028703

Abstract

Dihapto-coordination of aromatic molecules promotes numerous organic transformations that are not observed for the free aromatics. The development of osmium, rhenium, tungsten and molybdenum complexes that are capable of such binding is described in this perspective. The stability of these complexes strongly correlates to the metal d5/d6 reduction potential and electrochemical data has played a central role in their design.

摘要

芳香分子的双配位促进了许多游离芳烃未观察到的有机转化反应。本文综述了能够实现这种键合的锇、铼、钨和钼配合物的研究进展。这些配合物的稳定性与金属的d5/d6还原电位密切相关，电化学数据在其设计中起到了核心作用。