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通过中子活化分析测定生物材料中砷和锑的准确性和精密度方面。

Aspects of accuracy and precision in the determination of As and Sb in biological materials by neutron activation analysis.

作者信息

Woittiez J R, Geusebroek M

机构信息

Netherlands Energy Research Foundation E C N, Division of Chemistry and Material Sciences, Petten.

出版信息

Biol Trace Elem Res. 1990 Jul-Dec;26-27:561-9. doi: 10.1007/BF02992712.

DOI:10.1007/BF02992712
PMID:1704763
Abstract

Aspects of accuracy and precision of the determination of As and Sb in biological materials, using neutron activation with hydride generation, are discussed. It proves necessary to perform a yield determination for each sample. Both radiotracers and reactivation have been applied, and their practical use for yield correction is discussed. Results for several RMs are presented.

摘要

讨论了采用氢化物发生中子活化法测定生物材料中砷和锑的准确度和精密度方面的问题。事实证明有必要对每个样品进行产率测定。已应用放射性示踪剂和再活化方法,并讨论了它们在产率校正中的实际应用。给出了几个标准物质的结果。

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本文引用的文献

1
An automatic group separation system for the simultaneous determination of a great number of elements in biological material.
Anal Chem. 1968 Jan;40(1):181-7.
2
The toluene extraction of some elements as iodides from sulphuric acid-potassium iodide media. Application to neutron activation analysis. II. Determination of arsenic and antimony in biological materials at submicrogram levels.在硫酸-碘化钾介质中以碘化物形式对某些元素进行甲苯萃取。在中子活化分析中的应用。II. 生物材料中亚微克级砷和锑的测定。
Anal Chim Acta. 1972 Mar;59(1):91-9. doi: 10.1016/s0003-2670(01)84828-5.
3
Elemental characterization of the National Bureau of Standards Milk Powder Standard Reference Material by instrumental and radiochemical neutron activation analysis.通过仪器中子活化分析和放射化学中子活化分析对国家标准局奶粉标准参考物质进行元素表征。
Anal Chem. 1986 Oct;58(12):2511-6. doi: 10.1021/ac00125a034.
4
Trace elements in human clinical specimens: evaluation of literature data to identify reference values.人类临床样本中的微量元素:评估文献数据以确定参考值。
Clin Chem. 1988 Mar;34(3):474-81.