镧内嵌富勒烯C82与不饱和硫杂冠醚的超分子配合物
Supramolecular complexes of La@C82 with unsaturated thiacrown ethers.
作者信息
Tsuchiya Takahiro, Kurihara Hiroki, Sato Kumiko, Wakahara Takatsugu, Akasaka Takeshi, Shimizu Toshio, Kamigata Nobumasa, Mizorogi Naomi, Nagase Shigeru
机构信息
Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki, 305-8577, Japan.
出版信息
Chem Commun (Camb). 2006 Sep 14(34):3585-7. doi: 10.1039/b606183d. Epub 2006 Jul 17.
DOI:10.1039/b606183d
PMID:17047772
Abstract
The paramagnetic La@C82-A(C2v) with unsaturated thiacrown ethers forms 1 : 1 host-guest complexes of [La@C82-A(C2v)]-[D]+ in solution as a result of electron transfer.
摘要
具有不饱和硫杂冠醚的顺磁性La@C82 - A(C2v)在溶液中由于电子转移形成1:1的[La@C82 - A(C2v)] - [D]+主客体配合物。
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