Mori Masahiko, Kimura Masanari, Takahashi Yushi, Tamaru Yoshinao
Graduate School of Science and Technology, Nagasaki University, 1-14 Bunkyo, Nagasaki, 852-8521, Japan.
Chem Commun (Camb). 2006 Nov 4(41):4303-5. doi: 10.1039/b610164j. Epub 2006 Sep 1.
With a proper choice of phosphane ligands, a Ni(cod)2-phosphane catalyst promotes decarboxylative ring-opening reaction of a wide structural variety of cyclic carbonates to give omega-dienyl aldehydes in good yields.
通过适当选择膦配体，Ni(cod)2-膦催化剂能促进多种结构的环状碳酸酯发生脱羧开环反应，以良好的产率生成ω-二烯基醛。
