Zhu Jun, Kell Arnold J, Workentin Mark S
Department of Chemistry, The University of Western Ontario, London, Ontario, Canada N6A 5B7.
Org Lett. 2006 Oct 26;8(22):4993-6. doi: 10.1021/ol0615937.
Maleimide-modified monolayer-protected gold nanoparticles (MPGN) are prepared from the protected furan-maleimide via the thermally reversible Diels-Adler reaction when required. These maleimide-MPGNs serve as a general platform allowing for a Diels-Alder reaction with furan-modified MPN to prepare larger 3D networks reversibly. [reaction: see text]
马来酰亚胺修饰的单层保护金纳米颗粒（MPGN）在需要时通过热可逆的狄尔斯-阿尔德反应由受保护的呋喃-马来酰亚胺制备而成。这些马来酰亚胺-MPGN作为一个通用平台，允许与呋喃修饰的MPN发生狄尔斯-阿尔德反应，以可逆地制备更大的三维网络。[反应：见正文]
