铜（I）催化的炔基-叠氮化物环加成反应和呋喃-马来酰亚胺 Diels-Alder“点击”化学方法合成热敏树枝状聚合物。
Combined Cu(I)-catalysed alkyne-azide cycloaddition and furan-maleimide Diels-Alder "click" chemistry approach to thermoresponsive dendrimers.
机构信息
Department of Chemistry, McGill University, 801 Sherbrooke St. West, Montreal, Quebec, Canada H3A 2K6.
出版信息
Chem Commun (Camb). 2010 Mar 21;46(11):1875-7. doi: 10.1039/b924888a. Epub 2010 Jan 13.
DOI:10.1039/b924888a
PMID:20198238
Abstract
A divergent dendrimer construction methodology that employs Cu(I)-catalysed alkyne-azide cycloaddition (CuAAC) and furan-maleimide Diels-Alder (DA) "click" chemistry in a layer-by-layer fashion, is described. This synergistic approach yields dendrimers that undergo thermal disassembly via a retro-DA reaction.
摘要
一种采用铜（I）催化的炔烃-叠氮环加成（CuAAC）和呋喃-马来酰亚胺 Diels-Alder（DA）“点击”化学的层层方式构建树枝状大分子的方法。这种协同方法得到的树枝状大分子可以通过反 DA 反应进行热解组装。
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