Crawford James J, Henderson Kenneth W, Kerr William J
Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde, 295 Cathedral Street, Glasgow G1 1XL, Scotland, U.K.
Org Lett. 2006 Oct 26;8(22):5073-6. doi: 10.1021/ol061903l.
A general, one-pot process has been established to prepare ketones from aldehydes using N-tert-butylphenylsulfinimidoyl chloride. By employing the developed protocol, a range of unsymmetrical ketones has been prepared in good yields from aldehydes in one simple synthetic operation. [reaction: see text]
已建立了一种通用的一锅法，使用N-叔丁基苯基亚磺酰亚胺酰氯从醛制备酮。通过采用所开发的方案，在一个简单的合成操作中，从醛制备了一系列不对称酮，产率良好。[反应：见正文]
