Zhang Y, Causserand C, Aimar P, Cravedi J P
Department of Environmental Science, School of Chemistry and Life Science, ShenYang Normal University, No.253, Huanghe North Street, Shenyang, Liaoning, 110034, PR China.
Water Res. 2006 Dec;40(20):3793-9. doi: 10.1016/j.watres.2006.09.011. Epub 2006 Oct 30.
The efficiency with which a nanofiltration membrane (Desal 5 DK) removes bisphenol A (BPA) was investigated, together with the mechanisms involved. Whereas high retention (>90%) was obtained at the beginning of the filtration, the observed retention coefficient (R(obs)) decreased to around 50% when the membrane became saturated, due to adsorption of BPA onto the membrane structure. The presence of ions (Na+, Cl-) affects the R(obs), this effect being attributed to a change in BPA hydrodynamic radius. Moreover, in our operating conditions, the presence of natural organic matter (1mg/L) in the feed solution does not lead to variation in BPA retention at steady state.
研究了纳滤膜(Desal 5 DK)去除双酚A(BPA)的效率及其相关机制。在过滤开始时可获得较高的截留率(>90%),但当膜饱和时,由于BPA吸附到膜结构上,观察到的截留系数(R(obs))降至约50%。离子(Na+、Cl-)的存在会影响R(obs),这种影响归因于BPA流体动力学半径的变化。此外,在我们的操作条件下,进料溶液中天然有机物(1mg/L)的存在不会导致稳态下BPA截留率的变化。