可回收的聚合物锌（salen）配合物催化苯乙炔对醛和酮的对映选择性加成反应。
Enantioselective phenylacetylene addition to aldehydes and ketones catalyzed by recyclable polymeric Zn(salen) complex.
作者信息
Pathak Kavita, Bhatt Achyut P, Abdi Sayed H R, Kureshy Rukhsana I, Khan Noor-Ul H, Ahmad Irshad, Jasra Raksh V
机构信息
Silicates and Catalysis Discipline, Central Salt and Marine Chemicals Research Institute (CSMCRI), Bhavnagar 364 002, Gujarat, India.
出版信息
Chirality. 2007 Jan;19(1):82-8. doi: 10.1002/chir.20337.
New polymeric Zn(salen) complex was employed in the enantioselective phenylacetylene addition to aldehydes and ketones to produce corresponding chiral secondary propargylic alcohols with yields (up to 96%) and enantioselectivity (up to 72%) and tertiary propargylic alcohols with yields (up to 79%) and enantioselectivity (up to 68%) at room temperature, with added advantage of four times reuse with retention of enantioselectivity.
新型聚合物锌（salen）配合物被用于醛和酮的对映选择性苯乙炔加成反应，以在室温下生成相应的手性仲炔丙醇，产率高达96%，对映选择性高达72%，以及叔炔丙醇，产率高达79%，对映选择性高达68%，并且具有可重复使用四次且对映选择性保持不变的额外优势。
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