Rudzińska Ewa, Poliwoda Anna, Berlicki Łukasz, Mucha Artur, Dzygiel Paweł, Wieczorek Piotr P, Kafarski Paweł
Department of Bioorganic Chemistry, Faculty of Chemistry, Wrocław University of Technology, Wybrzeze Wyspiańskiego 27, 50-370 Wrocław, Poland.
J Chromatogr A. 2007 Jan 5;1138(1-2):284-90. doi: 10.1016/j.chroma.2006.10.065. Epub 2006 Nov 9.
Capillary electrophoresis was successfully applied for separation of the enantiomers of N-benzyloxycarbonyl-alpha-aminophosphonic and alpha-aminophosphinic acids as well as their ethyl and phenyl monoesters with the use of a range of commercially available cyclodextrins (alpha, beta and hydroxypropyl-gamma-cyclodextrins) as chiral selectors. The dependence of effectiveness of separation on type and concentration of these chiral selectors as well as on pH of background electrolyte was examined in some detail.
毛细管电泳已成功应用于分离N-苄氧羰基-α-氨基膦酸和α-氨基次膦酸及其乙酯和苯甲酯的对映体，使用了一系列市售的环糊精（α、β和羟丙基-γ-环糊精）作为手性选择剂。详细研究了分离效果对手性选择剂的类型和浓度以及背景电解质pH值的依赖性。
