硝酸铈铵促进恶唑的氧化反应。

Ceric ammonium nitrate promoted oxidation of oxazoles.

作者信息

Evans David A, Nagorny Pavel, Xu Risheng

机构信息

Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, USA.

出版信息

Org Lett. 2006 Nov 23;8(24):5669-71. doi: 10.1021/ol0624530.

DOI:10.1021/ol0624530

PMID:17107099

Abstract

The ceric ammonium nitrate promoted oxidations of 4,5-diphenyloxazoles and oxazoles with various substitution patterns have been investigated. This transformation results in the formation of the corresponding imide in good yield and tolerates a wide variety of functional groups and substituents on the oxazole moiety. [reaction: see text].

摘要

已对硝酸铈铵促进的4,5-二苯基恶唑和具有各种取代模式的恶唑的氧化反应进行了研究。这种转化以良好的产率生成相应的酰亚胺，并且恶唑部分上能耐受多种官能团和取代基。[反应：见正文]