微电极阵列与硝酸铈铵：开发新型位点选择性合成方法的简单策略。

Microelectrode arrays and ceric ammonium nitrate: a simple strategy for developing new site-selective synthetic methods.

作者信息

Kesselring David, Maurer Karl, Moeller Kevin D

机构信息

Department of Chemistry, Washington University, St. Louis, Missouri 63130, USA.

出版信息

J Am Chem Soc. 2008 Aug 27;130(34):11290-1. doi: 10.1021/ja804661h. Epub 2008 Aug 5.

DOI:10.1021/ja804661h

PMID:18680369

Abstract

Conditions for a site-selective ceric ammonium nitrate oxidation have been developed. The reactions proceed nicely on both 1K- and 12K-microelectrode arrays. The procedure for developing the reactions was very simple and demonstrated that the same reagents used for a solution-phase reaction can be used for a related site-selective reaction on a microelectrode array.

摘要

已经开发出了进行位点选择性硝酸铈铵氧化的条件。这些反应在1K和12K微电极阵列上都能顺利进行。开展这些反应的过程非常简单，并且表明用于溶液相反应的相同试剂可用于微电极阵列上相关的位点选择性反应。