Allabashi Roza, Arkas Michael, Hörmann Gerold, Tsiourvas Dimitris
Department Water-Atmosphere-Environment, University of Natural Resources and Applied Life Sciences, Institute for Sanitary Engineering and Water Pollution Control, Muthgasse 18, A-1190 Vienna, Austria.
Water Res. 2007 Jan;41(2):476-86. doi: 10.1016/j.watres.2006.10.011. Epub 2006 Nov 22.
Triethoxysilylated derivatives of poly(propylene imine) dendrimer, polyethylene imine and polyglycerol hyperbranched polymers and beta-cyclodextrin have been synthesized and characterized. These compounds impregnated ceramic membranes made from Al(2)O(3), SiC and TiO(2) and subsequently sol-gel reaction led to their polymerization and chemical bond formation with the ceramic substrates. The resulting organic-inorganic filters were tested for the removal of a variety of organic pollutants from water. They were found to remove of polycyclic aromatic hydrocarbons (up to 99%), of monocyclic aromatic hydrocarbons (up to 93%), trihalogen methanes (up to 81%), pesticides (up to 43%) and methyl-tert-butyl ether (up to 46%).
已合成并表征了聚(丙烯亚胺)树枝状大分子、聚乙烯亚胺和聚甘油超支化聚合物以及β-环糊精的三乙氧基硅烷化衍生物。这些化合物浸渍由Al(2)O(3)、SiC和TiO(2)制成的陶瓷膜,随后通过溶胶-凝胶反应实现它们的聚合以及与陶瓷基材形成化学键。对所得的有机-无机过滤器进行了测试,以去除水中的各种有机污染物。结果发现它们能去除多环芳烃(高达99%)、单环芳烃(高达93%)、三卤甲烷(高达81%)、农药(高达43%)和甲基叔丁基醚(高达46%)。