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采用浸渍有交联硅烷化树枝状聚合物和环糊精聚合物的陶瓷膜去除水中的一些有机污染物。

Removal of some organic pollutants in water employing ceramic membranes impregnated with cross-linked silylated dendritic and cyclodextrin polymers.

作者信息

Allabashi Roza, Arkas Michael, Hörmann Gerold, Tsiourvas Dimitris

机构信息

Department Water-Atmosphere-Environment, University of Natural Resources and Applied Life Sciences, Institute for Sanitary Engineering and Water Pollution Control, Muthgasse 18, A-1190 Vienna, Austria.

出版信息

Water Res. 2007 Jan;41(2):476-86. doi: 10.1016/j.watres.2006.10.011. Epub 2006 Nov 22.

Abstract

Triethoxysilylated derivatives of poly(propylene imine) dendrimer, polyethylene imine and polyglycerol hyperbranched polymers and beta-cyclodextrin have been synthesized and characterized. These compounds impregnated ceramic membranes made from Al(2)O(3), SiC and TiO(2) and subsequently sol-gel reaction led to their polymerization and chemical bond formation with the ceramic substrates. The resulting organic-inorganic filters were tested for the removal of a variety of organic pollutants from water. They were found to remove of polycyclic aromatic hydrocarbons (up to 99%), of monocyclic aromatic hydrocarbons (up to 93%), trihalogen methanes (up to 81%), pesticides (up to 43%) and methyl-tert-butyl ether (up to 46%).

摘要

已合成并表征了聚(丙烯亚胺)树枝状大分子、聚乙烯亚胺和聚甘油超支化聚合物以及β-环糊精的三乙氧基硅烷化衍生物。这些化合物浸渍由Al(2)O(3)、SiC和TiO(2)制成的陶瓷膜,随后通过溶胶-凝胶反应实现它们的聚合以及与陶瓷基材形成化学键。对所得的有机-无机过滤器进行了测试,以去除水中的各种有机污染物。结果发现它们能去除多环芳烃(高达99%)、单环芳烃(高达93%)、三卤甲烷(高达81%)、农药(高达43%)和甲基叔丁基醚(高达46%)。

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