Chemistry Institute of Natural Resources, Universidad de Talca, P.O. Box 747, Talca, Chile.
Núcleo Científico Multidisciplinario, Dirección de Investigación, Universidad de Talca, 3460000, Talca, Chile.
Environ Sci Pollut Res Int. 2018 Jan;25(3):2051-2064. doi: 10.1007/s11356-017-0796-2. Epub 2017 Nov 28.
The main organic pollutants worldwide are pesticides, persistent chemicals that are of concern owing to their prevalence in various ecosystems. In nature, pesticide remainders are subjected to the chemical, physical, and biochemical degradation process, but because of its elevated stability and some cases water solubility, the pesticide residues persist in the ecosystem. The removal of pesticides has been performed through several techniques classified under biological, chemical, physical, and physicochemical process of remediation from different types of matrices, such as water and soil. This review provides a description of older and newer techniques and materials developed to remove specific pesticides according to previous classification, which range from bioremediation with microorganisms, clay, activated carbon, and polymer materials to chemical treatment based on oxidation processes. Some types of pesticides that have been removed successfully to large and small scale include, organophosphorus, carbamates, organochlorines, chlorophenols, and synthetic pyrethroids, among others. The most important characteristics, advantages, and disadvantages of techniques and materials for removing pesticides are described in this work.
全世界主要的有机污染物是农药,这些持久性化学物质因其在各种生态系统中的普遍存在而引起关注。在自然界中,农药残留物会经历化学、物理和生物化学降解过程,但由于其稳定性较高且在某些情况下具有水溶性,因此农药残留会在生态系统中持久存在。已经采用了几种技术来去除农药,这些技术根据不同类型的基质(如水和土壤)分为生物、化学、物理和物理化学修复过程。本综述根据以前的分类,对为去除特定农药而开发的较旧和较新技术和材料进行了描述,范围从利用微生物、粘土、活性炭和聚合物材料的生物修复到基于氧化过程的化学处理。已经成功去除了包括有机磷、氨基甲酸酯、有机氯、氯酚和合成拟除虫菊酯在内的多种类型的农药,包括从小规模到大规模。本工作描述了去除农药的技术和材料的最重要特征、优点和缺点。