Xu G R, Zou J L, Dai Y
School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China.
Water Sci Technol. 2006;54(9):69-79. doi: 10.2166/wst.2006.755.
Dried sludge as additive for making ceramsite is a new effective approach for disposal of sludge. In this study sewage sludge, water glass and clay were chosen as the components, the optimal ratio of the components and the most appropriate conditions were obtained. The functions of primary components in the sintering process, porosity formation mechanism and solid phase reaction also have been discussed. The optimized process parameters were shown as follows: the ratio of dried sludge/clay (wt%) was 33%, ratio of adherent /clay (wt%) was 15%, sintering temperature was 1000 degrees C, sintering time was 10 min. Bulk density was 582 kg m(-3), particle density was 1,033 kg m(-3), water absorption was 9.5%, porosity was 43.7%. SEM, EDS, XRD and XRF analyses were also carried out. The results indicate that dried sludge as raw material is a good way for making ceramsite. Biological Aerated Filters (BAFs) with filter media of Guangzhou ceramsite, Jiangxi ceramsite, activated carbon and ceramsite (obtained in test) were selected to treat municipal wastewater. The average removal efficiencies of ceramsite (obtained in test) for turbidity, COD, SCOD and NH3-N were about 96.4%, 76.2%, 59.6% and 82.3% respectively and were higher than those of other ceramsites.
干污泥作为制备陶粒的添加剂是一种新型有效的污泥处置方法。本研究选用污水污泥、水玻璃和黏土作为原料,得出了各组分的最佳比例及最合适的条件。探讨了主要组分在烧结过程中的作用、孔隙形成机理及固相反应。优化后的工艺参数如下:干污泥/黏土(质量分数)为33%,黏附剂/黏土(质量分数)为15%,烧结温度为1000℃,烧结时间为10min。堆积密度为582kg·m⁻³,颗粒密度为1033kg·m⁻³,吸水率为9.5%,孔隙率为43.7%。还进行了扫描电子显微镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)和X射线荧光光谱仪(XRF)分析。结果表明,以干污泥为原料制备陶粒是一种可行的方法。选用以广州陶粒、江西陶粒、活性炭及本试验制备的陶粒为滤料的曝气生物滤池处理城市污水。本试验制备的陶粒对浊度、化学需氧量(COD)、溶解性化学需氧量(SCOD)和氨氮(NH₃-N)的平均去除率分别约为96.4%、76.2%、59.6%和82.3%,高于其他陶粒。