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基于铁尾矿的陶粒的物理化学性质表征。

Characterization of the Physical Chemistry Properties of Iron-Tailing-Based Ceramsite.

机构信息

School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, China.

Sinosteel Maanshan General Institute of Mining Research Co., Ltd., Maanshan City 243000, China.

出版信息

Molecules. 2023 Feb 28;28(5):2258. doi: 10.3390/molecules28052258.

Abstract

In order to deal with the problems of resource waste and environmental pollution caused by solid waste, iron tailings (mainly SiO, AlO and FeO) were used as the main raw material to create a type of lightweight and high-strength ceramsite. Iron tailings, dolomite (industrial grade, purity 98%) and a small amount of clay were combined in a N atmosphere at 1150 °C. X-ray fluorescence spectrometry (XRF), X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and a themogravimetric analysis (TGA) were performed and the specific surface area was analyzed to determine the strength and adsorption of the ceramsite. The results of the XRF showed that SiO, CaO and AlO were the main components of the ceramsite, with MgO and FeO also included. The results of the XRD and SEM-EDS showed that the ceramsite contained several kinds of minerals and was mainly composed of akermanite, gehlenite and diopside, and that the morphology of the internal structure of the ceramsite was mainly massive and contained a small number of particles. The ceramsite could be used in engineering practice to improve the mechanical properties of materials and meet the requirements of actual engineering for the strength of materials. The results of the specific surface area analysis showed that the inner structure of the ceramsite was compact and that there were no large voids. The voids were mainly medium and large, with a high stability and strong adsorption ability. The TGA results showed that the quality of the ceramsite samples will continue to increase within a certain range. According to the XRD experimental results and experimental conditions, it was speculated that in the part of the ore phase containing Al, Mg or Ca in the ceramsite, the elements underwent relatively complex chemical reactions with each other, resulting in the formation of an ore phase with a higher molecular weight. This research provides the basis of characterization and analysis for the preparation of high-adsorption ceramsite from iron tailings and promotes the high-value utilization of iron tailings for waste pollution control.

摘要

为了解决固体废物带来的资源浪费和环境污染问题,利用铁尾矿(主要成分为 SiO₂、Al₂O₃ 和 FeO)为主要原料,制备了一种轻质高强的陶粒。在 N 气氛中于 1150℃下,将铁尾矿、白云石(工业级,纯度 98%)和少量粘土组合在一起。采用 X 射线荧光光谱(XRF)、X 射线衍射(XRD)、扫描电子显微镜(SEM)、能谱(EDS)和热重分析(TGA)进行分析,并对比表面积进行了分析,以确定陶粒的强度和吸附性能。XRF 的结果表明,SiO₂、CaO 和 Al₂O₃ 是陶粒的主要成分,还包括 MgO 和 FeO。XRD 和 SEM-EDS 的结果表明,陶粒含有多种矿物,主要由钙镁橄榄石、钙长石和透辉石组成,内部结构的形态主要为块状,含有少量颗粒。该陶粒可用于工程实践,以提高材料的力学性能,满足实际工程对材料强度的要求。比表面积分析的结果表明,陶粒的内部结构致密,没有大的空隙。空隙主要为中大和较大,稳定性高,吸附能力强。TGA 的结果表明,在一定范围内,陶粒样品的质量会继续增加。根据 XRD 实验结果和实验条件,推测在陶粒中含有 Al、Mg 或 Ca 的矿相部分,元素之间发生了相对复杂的化学反应,形成了分子量较高的矿相。该研究为铁尾矿制备高吸附陶粒的表征和分析提供了基础,促进了铁尾矿在固废污染控制中的高值化利用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1a0/10005355/388f35b17a7f/molecules-28-02258-g001.jpg

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