（+）-绿胶霉素C的对映选择性全合成。
Enantioselective total synthesis of (+)-gliocladin C.
作者信息
Overman Larry E, Shin Youseung
机构信息
Department of Chemistry, 1102 Natural Sciences II, University of California, Irvine, California 92697-2025, USA.
出版信息
Org Lett. 2007 Jan 18;9(2):339-41. doi: 10.1021/ol062801y.
Abstract
The first total synthesis of gliocladin C, a fungal-derived marine alkaloid containing a rare trioxopiperazine fragment, is reported. This asymmetric synthesis establishes the absolute configuration of this structurally novel natural product. [reaction: see text].
摘要
据报道，首次全合成了来源于真菌的海洋生物碱胶枝菌素C，其含有一个罕见的三氧代哌嗪片段。这种不对称合成确定了这种结构新颖的天然产物的绝对构型。[反应：见正文]
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