Armstrong Alan, Baxter Carl A, Lamont Scott G, Pape Andrew R, Wincewicz Richard
Department of Chemistry, Imperial College London, South Kensington, London, SW7 2AZ, UK.
Org Lett. 2007 Jan 18;9(2):351-3. doi: 10.1021/ol062852v.
A novel method is presented using N-N ylides (prepared by in situ amination of a tertiary amine) for the aziridination of a range of enone systems. The amine may be used sub-stoichiometrically, and promising levels of enantioselectivity are observed with quinine as promoter. [reaction: see text].
本文介绍了一种使用N-氮叶立德（通过叔胺原位胺化制备）对一系列烯酮体系进行氮杂环丙烷化的新方法。胺可以以亚化学计量使用，并且以奎宁作为促进剂时观察到了有前景的对映选择性水平。[反应：见正文]
