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[十二烷基苯磺酸钠胶束中吖啶橙与罗丹明6G之间的能量转移机制研究]

[Study on the mechanism of energy transfer between acridine orange and rhodamine 6G in micelles of dodecyl benzene sodium sulfonate].

作者信息

Liu Bao-sheng, Sun Hua-yang, Liu Zhi-chao, Guo Yuan

机构信息

The Center of Physics and Chemistry, Hebei Provincial Key Laboratory of Analytical Science and Technology, Hebei University, Baoding 071002, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2006 Nov;26(11):2093-6.

Abstract

Applying Förster theory, the energy transfer between acridine orange (AO) and rhodamine 6G (R6G) was investigtaed. It was found that in the solution of dodecyl benzene sulfonic acid sodium (DBS), effective energy transfer can occur between AC and rhodamine 6G even when the concentration of the dyes is very low. The mechanism of energy transfer between AO and rhodamine 6G was studied. When the energy transfer occurs, the fluorescence of AO is quenched, the type of quenching is static. Based on the mechanism of Förster energy transference, the thermodynamic parameters, enthalpy change (deltaH) and entropy change (deltaS), were calculated according to Van't Hoff equation, which indicates the acting force between AO and R6G. The transfer efficiency of energy and the distance between AO and R6G were found. It is indicated that the course of action is single static quenching.

摘要

应用福斯特理论,研究了吖啶橙(AO)与罗丹明6G(R6G)之间的能量转移。发现在十二烷基苯磺酸钠(DBS)溶液中,即使染料浓度非常低,AC与罗丹明6G之间也能发生有效的能量转移。研究了AO与罗丹明6G之间的能量转移机制。当能量转移发生时,AO的荧光被猝灭,猝灭类型为静态。基于福斯特能量转移机制,根据范特霍夫方程计算了热力学参数,焓变(ΔH)和熵变(ΔS),这表明了AO与R6G之间的作用力。得出了能量转移效率以及AO与R6G之间的距离。结果表明作用过程为单一静态猝灭。

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