铑催化顺式烯丙基二醇与芳基硼酸酯的取代芳基化反应。
Rhodium-catalysed substitutive arylation of cis-allylic diols with arylboroxines.
作者信息
Miura Tomoya, Takahashi Yusuke, Murakami Masahiro
机构信息
Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan.
出版信息
Chem Commun (Camb). 2007 Feb 14(6):595-7. doi: 10.1039/b612710j. Epub 2006 Nov 8.
DOI:10.1039/b612710j
PMID:17264902
Abstract
Substitutive arylation of cis-allylic diols occurs upon treatment with arylboroxines in the presence of a rhodium(I) catalyst; the reaction proceeds through the addition of an intermediate arylrhodium(I) species across the carbon-carbon double bond and subsequent beta-oxygen elimination.
摘要
在铑（I）催化剂存在下，用芳基硼酸酯处理顺式烯丙基二醇时会发生取代芳基化反应；该反应通过中间体芳基铑（I）物种加成到碳-碳双键上并随后进行β-氧消除来进行。
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