X-ray photoreduction of a di(mu-oxo)Mn(III)Mn(IV) complex occurs at temperatures as low as 20 K.

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作者信息

Dubois Lionel, Jacquamet Lilian, Pécaut Jacques, Latour Jean-Marc

机构信息

Laboratoire DRDCIPMB, UMR 5155 CEA-CNRS- UJF, CEA-Grenoble, 38054 Grenoble Cedex 9, France.

出版信息

Chem Commun (Camb). 2006 Nov 21(43):4521-3. doi: 10.1039/b609072a.

DOI:10.1039/b609072a

PMID:17283805

Abstract

Full reduction of the Mn(III)(mu-O)2Mn(IV) core to Mn(II)(mu-OH2)2Mn(II) is observed upon irradiation by an X-ray beam at ca. 20 K.

摘要

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