金（III）催化邻炔基苯胺与端炔的双氢胺化反应生成N-乙烯基吲哚。
Gold(III)-catalyzed double hydroamination of o-alkynylaniline with terminal alkynes leading to N-vinylindoles.
作者信息
Zhang Yuhua, Donahue James P, Li Chao-Jun
机构信息
Department of Chemistry, Tulane University, New Orleans, Louisiana 70118, USA.
出版信息
Org Lett. 2007 Feb 15;9(4):627-30. doi: 10.1021/ol062918m.
PMID:17286370
Abstract
A highly efficient double-hydroamination reaction of o-alkynylanilines with terminal alkynes leading to N-alkenylindoles was developed by using gold(III) as a catalyst under neat conditions. [reaction: see text].
摘要
在无溶剂条件下，以金（III）为催化剂，开发了一种邻炔基苯胺与端炔的高效双氢胺化反应，生成N-烯基吲哚。[反应：见正文]
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