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[燃料油的微生物脱氮]

[Microbial denitrogenation of fuel oil].

作者信息

Li Shan-shan, Ma Ting, Li Guo-qiang, Liang Feng-lai, Liu Ru-lin

机构信息

College of Life Sciences, Nankai University, Tianjin 300071, China.

出版信息

Wei Sheng Wu Xue Bao. 2006 Dec;46(6):1023-7.

Abstract

The amount of organic nitrides contained in fuel oil is smaller than the one of organic sulfur compounds, but the existence of them is enough to affect the invariability of oil product greatly , and has a big effect on the color of oil. They also contribute to catalyst poisoning during the refining of crude oil, thus reducing the catalyzing rate of the catalyst and increasing process costs. Further more, some nitrogen organic compounds possess mutagenic and toxic activities. The combustion of these contaminants form nitrogen oxides (NOx), releasing of which to the air will cause the formation of acid rain and hence to air pollution. The classical hydroprocessing methods of nitrogen removal are costly and complicated, so the scientists are more and more interested in microbial denitrogenation. The aspects as follows are introduced, including the aromatic nitrogen compounds of fuel oil, the varieties of denitrogenation techincs, the classes of microbial denitrogenation and its biochemical pathways, molecular genetics developments of carbazole-degradative genes, and our opinion of the research direction in the future.

摘要

燃料油中有机氮化物的含量比有机硫化合物的含量少,但其存在足以极大地影响油品的稳定性,并对油品颜色有很大影响。它们还会在原油精炼过程中导致催化剂中毒,从而降低催化剂的催化速率并增加加工成本。此外,一些含氮有机化合物具有致突变和毒性活性。这些污染物燃烧形成氮氧化物(NOx),向空气中释放会导致酸雨形成,进而造成空气污染。传统的加氢处理脱氮方法成本高且复杂,因此科学家们对微生物脱氮越来越感兴趣。本文介绍了以下几个方面,包括燃料油中的芳香族氮化合物、脱氮技术的种类、微生物脱氮的类别及其生化途径、咔唑降解基因的分子遗传学进展,以及我们对未来研究方向的看法。

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